Silver Precipitates

Hazards

Avoid contact with silver compounds as they will stain skin and clothing.

Chemicals and Solutions

  • 0.1 M NaCO (1 mL)
  • 0.1 M AgNO (10 mL)
  • 0.1 M NaOH (10 mL)
  • 0.1 M NaCl (30mL)
  • 5 M NH (35 mL)
  • 0.1 M NaBr (10 mL)
  • 0.1 M NaSO (50 mL)
  • 0.1 M KI (10 mL)

Materials

  • 600 mL beaker
  • 200 mL water
  • Magnetic stirrer and bar

Procedure

  1. Add 200 mL water and a stirring bar to the 600 mL beaker and begin stirring.
  2. Starting with 1 mL of sodium carbonate add the solutions consecutively to the water in the order listed in the materials section. Precipitates will form and disappear.

Discussion

PrecipitateColorKspMoles/LNotes
AgCOwhite8.1 x 10-121.2 x 10-4most soluble
AgOHbrown6.8 x 10-98.2 x 10-5 
AgClwhite1.8 x 10-101.3 x 10-5 
AgBryellow7.7 x 10-138.8 x 10-7 
AgIyellow8.3 x 10-161.2 x 10-8least soluble