Chemicals and Solutions
- Copper electrode
- Stainless steel electrode
- Copper sulfate electrolyte (0.5M CuSO₄)
Materials
- Gotham cell (rectangular glass jar)
- D.C. power supply with alligator clips
- 2 - electrode holders
Procedure
- Show student the electrodes. Place electrodes in holders and in cell.
- Fill cell 3/4 full with CuSO₄ solution.
- Connect red clip to copper electrode, black clip to other.
- Use 6-8 volts D.C. You'll soon have a copper coating on the steel electrode. Show students copper coating.
- After use, reverse polarity and electroplate until copper just disappears from steel electrode. Do not allow to run any longer as solution would be ruined.
- If step 5 has been completed satisfactorily, return solution to stock bottle.
Discussion
The reaction:
At the copper anode:
\( \ce{ Cu_{(s)} -> Cu+_{(aq)} + 2e- } \)
At the stainless steel cathode:
\( \ce{ Cu2+_{(aq)} + 2e- -> Cu_{(s)} } \)