Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds

RS-Fe(IV)=O ORTEP and HAT deuterium isotope effect

Dedushko, M. A.; Greiner, M. B.; Downing, A. N.; Coggins, M. K.; *Kovacs, J. A. “Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds.” J. Am. Chem. Soc. 2022,144, 8515-8528

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